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Electron and phonon transports in CaMnO3 and its Bi-doped counterpart, Bi0.03Ca0.97MnO3, are investigated by thermoelectric transport measurements, Raman spectroscopy, and first-principles calculations. In particular, we focus on CaMnO3 and Bi0.03Ca0.97MnO3’s electronic structures, temperature-dependent electron and phonon lifetimes, and their sound velocities. We find that the anti
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Donor-doped CaMnO3 is an n-type semiconductor with perovskite structure, being considered as a potential n-type leg in thermoelectric modules. This oxide presents stability at high temperatures and allows tuning the relevant electrical and thermal transport properties through doping. In this work, Ca0.9Gd0.1MnO3 precursors have been prepared to produce fibres through the laser floating zone
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Calcium manganite CaMnO 3, an n-type perovskite oxide, The effects of particle sizes, produced by different ball mill time durations, on microstructures and TE performances of Ca 0.9 Yb 0.1 MnO 3 ceramics have been systematically studied. The reduced particle size, due to the longer milling time, increases the sintered density at particular sintering temperature. It is also found that
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